Current Work:

1. de Alwis, C.; Wahr, K.; Perrine, K. A. Influence of Cations on CO2 Direct Capture and Mineral Film Formation: The Role of KCl and MgCl2 at the Air/Electrolyte/Iron Interface. J. Phys. Chem. A, 2024 128 (20), 4052-4067.

Featured on the supplementary cover:

2. de Alwis, C.; Perrine, K. A. Dechlorination of CDCl3 on Fe(111): Implications for disinfection by-product degradation. Surface Science 2023 (732), 122271.

3. de Alwis, C.; Trought, M.; Crumlin, E.; Nemsak, S.; Perrine, K. A. Probing the initial stages of iron surface corrosion: Effect of O2 and H2O on surface carbonation. Applied Surface Science, 2023 (612),155596; published online Nov. 2022.

4. de Alwis, C.; Trought, M.; Lundeen, J.; Perrine, K. A. Effect of Cations on the Oxidation and Atmospheric Corrosion of Iron Interfaces to Minerals. J. Phys. Chem. A, 2021 125 (36), 8047-8063.

5. Trought, M.; Perrine, K. A. Investigating the Relationship between Adhesion Forces and Surface Functionalization Using Atomic Force Microscopy. J. Chem. Educ., 2021 98 (5), 1768-1775.

6. de Alwis, C.; Perrine, K. A. In Situ PM-IRRAS at the Air/Electrolyte/Solid Interface Reveals Oxidation of Iron to Distinct MineralsJ. Phys. Chem. A., 2020 124 (33), 6735-6744. doi/10.1021/acs.jpca.0c03592

7. Trought, M.; Wentworth, I.; Leftwich, T. R.; Perrine, K. A. ; Effects of Wet Chemical Oxidation on Surface Functionalization and Morphology of Highly Oriented Pyrolytic Graphite. ChemRxiv. Preprint. 2020. 

8. de Alwis, C.; Leftwich, T. R..; Perrine, K. A. New Approach to Simultaneous In Situ Measurement of the Air/Liquid/Solid Interface using PM-IRRAS. Langmuir, 2020 36 (13), 3404-3414.

9. Degaga, G.; Trought, M.; Nemsak, S.; Crumlin, E., Pandey, R.; Seel, M.; Perrine, K. A. Investigation of N2 Adsorption on Fe3O4(001) using Ambient Pressure Photoelectron Spectroscopy and Density Functional Theory. J. Chem. Phys., 2020 152, 054717. *special edition on Oxide Chemistry and Catalysis article (invited). **chosen as a feature article.

10. Zhan, R.; Payne, T.; Leftwich, T. R.; Perrine, K. A.; Pan, L. De-agglomeration of Cathode Composites from Current Collectors for Li-ion Battery Recycling. Waste Management, 2020 105, 39-48.

11. de Alwis, C.; Leftwich, T. R.; Mukherjee, P.; Denofre, A.; Perrine, K. A. Spontaneous Selective Deposition of Iron Oxide Nanoparticles on Graphite as model catalysts. Nanoscale Advances, 2019 1 (12), 4729-4744.

12. Forooshani, P. K.; Polega, E.; Thomson, K.; Akream, M. S.; Pinnaratip, R.; Trought, M.; Kendrick, C.; Gao, Y.; Perrine, K. A.; Pan, L.; Lee, B. P.; Antibacterial Properties of Mussel-Inspired Polydopamine Coatings Prepared by Simple Two-Step Shaking-Assisted Method. Frontiers in Chemistry, 2019; 7(631), 471706.

13. Trought, M. A.; Wentworth, I.; de Alwis, C.; Leftwich, T. R.; Perrine, K. A. Influence of surface etching and oxidation on the morphological growth of Al2O3 by ALD Surface Science, 2019 (690) 121479. *highlighted on cover.

14. Trought, M. A.; Wentworth, I.; Leftwich, T. R.; Perrine, K. A. Investigation of Selective Growth of ALD Alumina on Functionalized HOPG Surfaces. Abstracts from the American Chemical Society, 256th conference;  Boston, MA Aug. 2018.

15. Perrine, K.A.; Trought, M. A.; Nemsak, S.; Crumlin, E. Understanding Adsorption Processes on Iron Oxide Surfaces for Ammonia Formation Using Ambient Pressure-XPS. Abstracts from the American Chemical Society, 256th conference; Boston, MA Aug. 2018.

Previous work:

1. Perrine, K. A.; Parry, K. M.; Stern, A. C.; Van Spyk, M. H. C.; Makowski, M. J.; Freites, J. A.; Winter; B., Tobias, D. J.; Hemminger, J. C. Specific cation effects at aqueous solution-vapor interfaces: surfactant-like behavior of Li+ revealed by experiments and simulations. Proc. Natl. Acad. Sci. U.S.A., 2017 114 (51) 1336313368. doi: 10.1073/pnas.1707540114 link

2. Perrine, K. A.; Van Spyk, M. H. C.; Margarella, A. M.; Winter, B.; Faubel, M.; Bluhm H.; Hemminger, J. C. Characterization of the acetonitrile aqueous solution/vapor interface by Liquid-Jet X-ray photoelectron spectroscopy. J. Phys. Chem. C, 2014 118 (50), 29378-29388. link

3. Margarella, A. M.; Perrine, K. A.; Lewis, T.; Faubel, M.; Winter, B.; Hemminger, J. C. Dissociation of sulfuric acid in aqueous solution: determination of the photoelectron spectral fingerprints of H2SO4, HSO4- and SO4- in water. J. Phys. Chem. C, 2013 117 (16), 8131-8137. link

4. Perrine, K. A.; Lin, J.-M..; Teplyakov, A. V. Controlling the formation of metallic nanoparticles on functionalized silicon surfaces. J. Phys. Chem. C, 2012 116 (27), 14431-14444. link

5. Perrine, K. A.; Rodríguez-Reyes, J. C. F.; Teplyakov, A. V. Simulating the reactivity of disordered surfaces: TiCN thin films. J. Phys. Chem. C, 2011 115 (31), 15432-15439. link

6. Perrine, K. A.; Teplyakov, A. V. Metallic nanostructure formation limited by the surface hydrogen on silicon. Langmuir, 2010 26 (15), 12648-12658. link

7. Perrine, K. A.; Teplyakov, A. V. Reactivity of Selectively Terminated Single Crystal Silicon Surfaces. Chem. Soc. Rev., 2010 39 (8), 3256-3274. link

8. Perrine, K. A.; Leftwich, T. R.; Weiland, C. R.; Madachik, M.; Opila, R. L.; Teplyakov, A. V. Reactions of aromatic bifunctional molecules on silicon surfaces: nitrosobenzene and nitrobenzene. J. Phys. Chem. C, 2009 113 (16), 6643-6653. link

9. Perrine, K. A.; Skliar, D. B.; Willis, B.; Teplyakov, A. V. Molecular Level Investigation of 2,2,6,6-tetramethyl-3,5-heptanedione on Si(100)-2×1: Spectroscopic and Computational Studies. Surface Science, 2008 602 (13), 2222-2231. link

10. Ozturk, O.; Black, T. J.; Perrine, K.; Pizzolato, K; Williams, C. T.; Parsons, F. W.; Ratliff, J. S.; Gao, J.; Murphy, C. J.; Xie, H.; Ploehn, H. J.; Chen, D. A. Thermal Decomposition of Generation-4 Polyamidoamine Dendrimer Films: Decomposition Catalyzed by Dendrimer-Encapsulated Pt Particles. Langmuir 2005 21 (9), 3998-4006. link

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